Infoscience

Patent

Chlorosulfonic acid

High-purity HSO3Cl is prepd. at a high space-time yield by mixing and reacting gaseous HCl with SO3 dissolved in ClSO3H, contg. 0.3-1.4% SO3 at 70-100 Deg in a venturi tube at 1-1.1 mol HCl/mol SO3. Thus, into the throat of a vertical venturi tube was fed gaseous HCl at 520 L/h and a rising stream of a soln. of SO3 in HSO3Cl. The reaction mixt. at 80 Deg then passed into the bubble column above the venturi where the reaction was completed, excess HCl being discharged at the top of the column, and HSO3Cl withdrawn through a side outlet and cooled. The product was collected at an outlet at 2.9 kg/h. The remaining CSO3Cl was recycled to the venturi reactor after the addn. of 1.05 L SO3/h. [on SciFinder (R)]

    Keywords: chlorosulfuric acid manuf; sulfur trioxide reaction; hydrochloric acid reaction

    Note:

    CAN 90:189237

    49-2

    Industrial Inorganic Chemicals

    Patent

    written in German.

    19790118

    7790-94-5P Role: IMF (Industrial manufacture), PREP (Preparation) (manuf. of, app. for); 7446-11-9 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with hydrochloric acid, app. for); 7647-01-0P Role: RCT (Reactant), PREP (Preparation), RACT (Reactant or reagent) (reaction of, with sulfur trioxide, app. for)

    Reference

    Record created on 2006-04-18, modified on 2016-08-08

Fulltext

  • There is no available fulltext. Please contact the lab or the authors.

Related material