Influence of periodic concentration variations on the product distribution during the oxidation of hydrocarbons

The influence of forced concn. variations on the oxidn. of hydrocarbons over a Pt gauze catalyst was examd. The period was varied between 0 and 120 sec. The periodic method of operation avoided temp. problems occurring at high conversions under stationary conditions. In the oxidn. of butane, the mean catalyst temp. could be maintained at 252-332 Deg. In the oxidn. of cyclohexene, the influence on product distribution (CO-CO2) of the kind of process operation was shown. The selectivity of the intermediate CO was 7-55%, according to the time period. [on SciFinder (R)]


Published in:
Chemie Ingenieur Technik, 45, 12, 854-859
Year:
1973
Keywords:
Note:
CAN 79:78178
24-5
Alicyclic Compounds
Inst. Tech. Chem.,Tech. Univ. Hannover,Hanover,Fed. Rep. Ger.
Journal
0009-286X
written in German.
124-38-9P; 630-08-0P Role: PREP (Preparation) (by hydrocarbon oxidn., periodic concn. variations in relation to); 106-97-8; 110-83-8 Role: RCT (Reactant), RACT (Reactant or reagent) (oxidn. of, periodic concn. variations in relation to); 115-07-1 Role: RCT (Reactant), RACT (Reactant or reagent) (oxidn. of, temp. hysteresis)
Laboratories:




 Record created 2006-04-18, last modified 2018-03-17


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)