A large-scale low-cost access to the lithium 2,2,6,6-tetramethylpiperidide precursor
Kampmann, Detlef; Stuhlmueller, Georg; Simon, Roger; Cottet, Fabrice; Leroux, Frederic; Schlosser, Manfred
2005

Abstract

Wolff-Kishner-Huang redn. of the cheap 2,2,6,6-tetramethyl-4-piperidinone provides the expensive 2,2,6,6-tetramethylpiperidine, the precursor to lithium 2,2,6,6-tetramethylpiperidide, in high yield. As specified in the detailed protocol, the reaction can be conveniently carried out on a >10 mol lab. scale. [on SciFinder (R)]

Details

Title A large-scale low-cost access to the lithium 2,2,6,6-tetramethylpiperidide precursor
Author(s) Kampmann, Detlef ; Stuhlmueller, Georg ; Simon, Roger ; Cottet, Fabrice ; Leroux, Frederic ; Schlosser, Manfred
Published in Synthesis
Issue 6
Pages 1028-1029
Date 2005
ISSN 0039-7881
Keywords
Note CAN 142:392262
27-16
Heterocyclic Compounds (One Hetero Atom)
Gersthofen,Germany.
Journal
written in English.
826-36-8 (2,2,6,6-Tetramethyl-4-piperidinone) Role: RCT (Reactant), RACT (Reactant or reagent) (prepn. of 2,2,6,6-tetramethylpiperidine by Wolff-Kishner-Huang redn. of 2,2,6,6-tetramethyl-4-piperidinone); 768-66-1P (2,2,6,6-Tetramethylpiperidine) Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of 2,2,6,6-tetramethylpiperidine by Wolff-Kishner-Huang redn. of 2,2,6,6-tetramethyl-4-piperidinone)
DOI https://doi.org/10.1055/s-2004-834856
Other identifier(s) View record in Web of Science
DAR: 6785
Laboratories LSCO
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2006-03-03