000081649 001__ 81649
000081649 005__ 20181203020331.0
000081649 0247_ $$2doi$$a10.1016/0040-4020(95)00250-C
000081649 037__ $$aARTICLE
000081649 245__ $$aThe selective O-acylation of enolates providing simple entry to O-enesters
000081649 260__ $$c1995
000081649 269__ $$a1995
000081649 336__ $$aJournal Articles
000081649 500__ $$aCAN 123:255835
000081649 500__ $$a21-2
000081649 500__ $$aGeneral Organic Chemistry
000081649 500__ $$aInst. Chim. Org.,Univ. Batiment Chim.,Lausanne-Dorigny,Switz.
000081649 500__ $$aJournal
000081649 500__ $$a0040-4020
000081649 500__ $$awritten in English.
000081649 500__ $$a16984-48-8 (Fluoride) Role: CAT (Catalyst use), USES (Uses) (selective O-acylation of enolates providing simple entry to O-enesters); 75-36-5 (Acetyl chloride); 79-03-8 (Propanoyl chloride); 93-97-0; 98-88-4 (Benzoyl chloride); 108-24-7 (Acetic anhydride); 112-67-4 (Hexadecanoyl chloride); 123-62-6; 334-19-0 (Heptanoyl fluoride); 430-71-7 (Propionyl fluoride); 430-92-2 (Isobutyryl fluoride); 455-32-3 (Benzoyl fluoride); 532-24-1 (Tropinone); 557-99-3 (Acetyl fluoride); 626-27-7; 1598-93-2 (10-Undecenoyl fluoride); 2528-61-2 (Heptanoyl chloride); 3872-13-7 (Hexadecanoyl fluoride); 6213-94-1; 6651-36-1; 19980-22-4; 36045-78-0; 50300-19-1; 52186-50-2; 52387-36-7 (6-Chlorohexanal); 56219-03-5; 63383-46-0; 65405-70-1 (trans-4-Decenal); 71504-21-7; 73912-36-4; 146271-53-6; 146271-54-7; 169216-34-6; 169216-35-7; 169216-48-2 Role: RCT (Reactant), RACT (Reactant or reagent) (selective O-acylation of enolates providing simple entry to O-enesters); 42082-93-9P; 121846-51-3P; 169216-37-9P; 169216-38-0P; 169216-39-1P; 169216-40-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (selective O-acylation of enolates providing simple entry to O-enesters); 115-22-0P; 693-38-9P (Vinyl palmitate); 2424-36-4P; 19980-23-5P; 57576-60-0P; 74322-79-5P; 84262-84-0P; 93675-37-7P; 165614-45-9P; 165614-47-1P; 165614-50-6P; 165614-51-7P; 165614-52-8P; 165614-53-9P; 169216-41-5P; 169216-42-6P; 169216-43-7P; 169216-44-8P; 169216-45-9P; 169216-46-0P; 169216-47-1P Role: SPN (Synthetic preparation), PREP (Preparation) (selective O-acylation of enolates providing simple entry to O-enesters)
000081649 520__ $$aIn the presence of catalytic amts. of a fluoride source, O-trimethylsilyl enethers undergo condensation with acyl fluorides to afford O-enesters with high yields. The intermediates and final products are pure (Z) isomers if only one double bond is in conjugation with the oxygen atom whereas (E) isomers prevail if silyl dienethers or trienethers and O-dienesters or O-triensesters are formed. [on SciFinder (R)]
000081649 6531_ $$aStereochemistry (selective O-acylation of enolates providing simple entry to O-enesters); Esters Role: SPN (Synthetic preparation)
000081649 6531_ $$aPREP (Preparation) (selective O-acylation of enolates providing simple entry to O-enesters); Ethers Role: RCT (Reactant)
000081649 6531_ $$aselective acylation enolate; enol ester
000081649 700__ $$aLimat, Dominique
000081649 700__ $$0240930$$aSchlosser, Manfred$$g123541
000081649 773__ $$j51$$k20$$q5799-806$$tTetrahedron
000081649 909C0 $$0252181$$pLSCO
000081649 909CO $$ooai:infoscience.tind.io:81649$$particle
000081649 937__ $$aLSCO-ARTICLE-1995-004
000081649 970__ $$a130/LSCO
000081649 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000081649 980__ $$aARTICLE