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Journal article

O-Fluoromethyl carboxylates and O-fluoromethyl carbamates

The fluoride catalyzed reaction between acyl fluorides and monomeric formaldehyde affords fluoromethyl carboxylates in acceptable yields. Fluoromethyl fluoroformate, readily accessible from the corresponding dichloro compd., condenses with amines to give fluoromethyl carbamates. [on SciFinder (R)]

    Keywords: Acetalization and Ketalization; Addition reaction; Addition reaction catalysts (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); Acid fluorides; Amines Role: RCT (Reactant) ; RACT (Reactant or reagent) (O-fluoromethyl carboxylates and O-fluoro ; carboxylate fluoromethyl; carbamate fluoromethyl

    Note:

    CAN 123:142990

    21-2

    General Organic Chemistry

    Inst. CHim. Org.,Univ. Batiment Chim.,Lausanne-Dorigny,Switz.

    Journal

    0040-4020

    written in English.

    5342-31-4P (Methylene dibenzoate); 20177-68-8P; 32720-34-6DP; 166331-88-0P; 166331-89-1P Role: BYP (Byproduct), PREP (Preparation) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 17455-13-9 (18-Crown-6); 59201-86-4 (Tris(diethylamino)sulfonium difluorotrimethylsilicate) Role: CAT (Catalyst use), USES (Uses) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 7789-23-3 (Potassium fluoride) Role: CAT (Catalyst use), RCT (Reactant), USES (Uses), RACT (Reactant or reagent) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 100-46-9 (Benzylamine); 104-94-9 (p-Anisidine); 109-73-9 (Butylamine); 136-95-8 (2-Aminobenzothiazole); 288-32-4 (Imidazole); 334-19-0 (Heptanoyl fluoride); 455-32-3 (Benzoyl fluoride); 693-34-5 (Adipoyl fluoride); 1977-87-3 (Cyclohexanecarbonyl fluoride); 22128-62-7 (Chloromethyl chloroformate); 31174-04-6 (2-Furoyl fluoride) Role: RCT (Reactant), RACT (Reactant or reagent) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 2838-04-2P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 166331-78-8P; 166331-79-9P; 166331-80-2P; 166331-81-3P; 166331-82-4P; 166331-83-5P; 166331-84-6P; 166331-85-7P; 166331-86-8P; 166331-87-9P Role: SPN (Synthetic preparation), PREP (Preparation) (O-fluoromethyl carboxylates and O-fluoromethyl carbamates); 50-00-0 (Formaldehyde) Role: RCT (Reactant), RACT (Reactant or reagent) (monomeric; O-fluoromethyl carboxylates and O-fluoromethyl carbamates)

    Reference

    Record created on 2006-03-03, modified on 2016-08-08

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