The spontaneous cyclodimerization of 2,3-dihydroisoquinolines after base promoted elimination of methanol from 4-methoxy-1,2,3,4-tetrahydroisoquinolines
1994
Résumé
The reaction of 4-methoxy-1,2,3,4-tetrahydroisoquinolines I (R = MeO, R1 = H; RR1 = OCH2O) with Li diisopropylamide affords dimerization products II. The intermediacy of orthoquinodimethanes and diradicals is assumed. [on SciFinder (R)]
Détails
Titre
The spontaneous cyclodimerization of 2,3-dihydroisoquinolines after base promoted elimination of methanol from 4-methoxy-1,2,3,4-tetrahydroisoquinolines
Auteur(s)
Simig, Glyula ; Schlosser, Manfred
Publié dans
Tetrahedron Letters
Volume
35
Numéro
19
Pages
3081-2
Date
1994
ISSN
0040-4039
Mots-clés (libres)
Note
CAN 121:108568
28-2
Heterocyclic Compounds (More Than One Hetero Atom)
Inst. Chim.,Univ. Rue de la Barre,Lausanne,Switz.
Journal
written in English.
156634-87-6P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and crystal and mol. structure of); 156634-89-8P; 156634-90-1P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and cyclodimerization of); 156634-88-7P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
28-2
Heterocyclic Compounds (More Than One Hetero Atom)
Inst. Chim.,Univ. Rue de la Barre,Lausanne,Switz.
Journal
written in English.
156634-87-6P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and crystal and mol. structure of); 156634-89-8P; 156634-90-1P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and cyclodimerization of); 156634-88-7P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
Laboratoires
LSCO
Le document apparaît dans
Production scientifique et compétences > SB - Faculté des sciences de base > SB Archives > LSCO - Laboratoire de synthèse organique et catalyse
Publications validées par des pairs
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Articles de journaux
Publié
Publications validées par des pairs
Travail produit à l'EPFL
Articles de journaux
Publié
Date de création de la notice
2006-03-03