The spontaneous cyclodimerization of 2,3-dihydroisoquinolines after base promoted elimination of methanol from 4-methoxy-1,2,3,4-tetrahydroisoquinolines
Simig, Glyula; Schlosser, Manfred
1994

Abstract

The reaction of 4-methoxy-1,2,3,4-tetrahydroisoquinolines I (R = MeO, R1 = H; RR1 = OCH2O) with Li diisopropylamide affords dimerization products II. The intermediacy of orthoquinodimethanes and diradicals is assumed. [on SciFinder (R)]

Details

Title The spontaneous cyclodimerization of 2,3-dihydroisoquinolines after base promoted elimination of methanol from 4-methoxy-1,2,3,4-tetrahydroisoquinolines
Author(s) Simig, Glyula ; Schlosser, Manfred
Published in Tetrahedron Letters
Volume 35
Issue 19
Pages 3081-2
Date 1994
ISSN 0040-4039
Keywords
Note CAN 121:108568
28-2
Heterocyclic Compounds (More Than One Hetero Atom)
Inst. Chim.,Univ. Rue de la Barre,Lausanne,Switz.
Journal
written in English.
156634-87-6P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and crystal and mol. structure of); 156634-89-8P; 156634-90-1P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and cyclodimerization of); 156634-88-7P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
DOI https://doi.org/10.1016/S0040-4039(00)76833-X
Laboratories LSCO
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2006-03-03

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