Infoscience

Journal article

A shortcut to a-santalol

a-Santalol (Z-I) can be prepd. from the readily available 8-bromotricyclene (II) in a one-flask procedure under perfect regio- and stereocontrol. [on SciFinder (R)]

    Keywords: Regiochemistry; Stereochemistry (of hydroxylation of b-santalene); Alkylation (of potassioisoprene by bromotricyclene ; a-santalene from); Hydroxylation (of a-santalene ; regioselective and stereoselectivity in) ; santalol regiocontrolled stereocontrolled total synthesis; bromotricyclene stereocontrolled conversion santalol

    Note:

    CAN 120:107378

    30-15

    Terpenes and Terpenoids

    Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.

    Journal

    0040-4039

    written in English.

    152578-86-4 Role: RCT (Reactant), RACT (Reactant or reagent) (agent for hydroxylation of a-santalene); 52645-83-7 Role: RCT (Reactant), RACT (Reactant or reagent) (alkylation by, of potassioisoprene, a-santalene from); 152096-85-0 Role: RCT (Reactant), RACT (Reactant or reagent) (coupling reaction of, with (methallyl)magnesium chloride); 152096-83-8P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and epoxide rearrangement of); 22527-23-7P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and hydroxylation of, regio- and stereocontrol in); 152186-23-7P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and isomerization of); 153838-36-9P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and oxidn. of); 19903-70-9P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and redn. of); 115-71-9P (a-Santalol); 14490-17-6P; 152096-84-9P; 152186-24-8P; 152186-25-9P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 152186-26-0 Role: RCT (Reactant), RACT (Reactant or reagent) (tosylation of)

    Reference

    Record created on 2006-03-03, modified on 2016-08-08

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