A one-pot synthesis of coumaryl, coniferyl, and sinapyl alcohol
1991
Abstract
The side chain of 4-allylphenols was easily deprotonated by BuLi-KOCMe3. Consecutive treatment with FB(OMe)2 and H2O2 afforded the title alcs. I (R = H, R1 = H, OMe; R = R1 = OMe). [on SciFinder (R)]
Details
Title
A one-pot synthesis of coumaryl, coniferyl, and sinapyl alcohol
Author(s)
Rothen, Laure ; Schlosser, Manfred
Published in
Tetrahedron Letters
Volume
32
Issue
22
Pages
2475-6
Date
1991
ISSN
0040-4039
Keywords
Note
CAN 115:28970
26-9
Biomolecules and Their Synthetic Analogs
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in English.
97-53-0 (Eugenol); 501-92-8 (4-Allylphenol); 6627-88-9 Role: RCT (Reactant), RACT (Reactant or reagent) (hydroxylation and isomerization of); 118-34-3P (Syringin); 458-35-5P (Coniferyl alcohol); 531-29-3P (Coniferin); 537-33-7P (Sinapyl alcohol); 20649-40-5P (Coumaryl alcohol); 134660-05-2P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 572-09-8 (Acetobromoglucose) Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with hydroxypropenylphenols)
26-9
Biomolecules and Their Synthetic Analogs
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in English.
97-53-0 (Eugenol); 501-92-8 (4-Allylphenol); 6627-88-9 Role: RCT (Reactant), RACT (Reactant or reagent) (hydroxylation and isomerization of); 118-34-3P (Syringin); 458-35-5P (Coniferyl alcohol); 531-29-3P (Coniferin); 537-33-7P (Sinapyl alcohol); 20649-40-5P (Coumaryl alcohol); 134660-05-2P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 572-09-8 (Acetobromoglucose) Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with hydroxypropenylphenols)
Laboratories
LSCO
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2006-03-03