Ring tension, hydrocarbon acidity, and new super-bases
1986
Abstract
Addn. of di-Na pinacolate or KOCMe3 increased the transmetalating power of pentylsodium in alkane solvents. Some hydrocarbons thus metalated were Me3CCH:CH2, camphene, bicyclo[2.2.2]octene, spiro[4.4]nona-1,3-diene, nortricyclane, norcarane, and housane. Cyclobutanes remained inert. [on SciFinder (R)]
Details
Title
Ring tension, hydrocarbon acidity, and new super-bases
Author(s)
Schlosser, Manfred ; Hartmann, Juergen ; Staehle, Manfred ; Kramar, Jaroslav ; Walde, Annelies ; Mordini, Alessandro
Published in
Chimia
Volume
40
Issue
9
Pages
306-308
Date
1986
ISSN
0009-4293
Keywords
Hydrocarbons Role: RCT (Reactant); RACT (Reactant or reagent) (transmetalation of; by pentylsodium; effect of activators on); Bases Role: RCT (Reactant); RACT (Reactant or reagent) (super-; pentylsodium with disodium pinacolate or potassium tert-butoxid; transmetalation hydrocarbon pentylsodium pinacolate butoxide; pinacolate effect hydrocarbon transmetalation pentylsodium; butoxide effect hydrocarbon transmetalation pentylsodium
Note
CAN 107:59068
29-2
Organometallic and Organometalloidal Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in English.
287-23-0 (Cyclobutane); 4755-33-3; 4806-58-0; 4806-59-1; 15358-91-5 (trans-Myrtanol) Role: RCT (Reactant), RACT (Reactant or reagent) (attempted transmetalation of, by pentylsodium); 865-47-4; 109289-48-7 (Disodium pinacolate) Role: PRP (Properties) (effect of, on transmetalation of hydrocarbons by pentylsodium); 2716-23-6P; 2987-16-8P; 20107-37-3P; 31297-51-5P; 36744-59-9P; 40154-85-6P; 54382-52-4P; 57566-92-4P; 64081-43-2P; 109263-32-3P; 109263-33-4P; 109289-47-6P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 1822-71-5 (Pentylsodium) Role: RCT (Reactant), RACT (Reactant or reagent) (transmetalation by, of hydrocarbons, effect of activators on); 79-92-5 (Camphene); 185-94-4 (Housane); 279-19-6; 286-08-8; 558-37-2 (3,3-Dimethyl-1-butene); 766-29-0; 931-64-6 Role: RCT (Reactant), RACT (Reactant or reagent) (transmetalation of, by pentylsodium, effect of activators on)
29-2
Organometallic and Organometalloidal Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in English.
287-23-0 (Cyclobutane); 4755-33-3; 4806-58-0; 4806-59-1; 15358-91-5 (trans-Myrtanol) Role: RCT (Reactant), RACT (Reactant or reagent) (attempted transmetalation of, by pentylsodium); 865-47-4; 109289-48-7 (Disodium pinacolate) Role: PRP (Properties) (effect of, on transmetalation of hydrocarbons by pentylsodium); 2716-23-6P; 2987-16-8P; 20107-37-3P; 31297-51-5P; 36744-59-9P; 40154-85-6P; 54382-52-4P; 57566-92-4P; 64081-43-2P; 109263-32-3P; 109263-33-4P; 109289-47-6P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 1822-71-5 (Pentylsodium) Role: RCT (Reactant), RACT (Reactant or reagent) (transmetalation by, of hydrocarbons, effect of activators on); 79-92-5 (Camphene); 185-94-4 (Housane); 279-19-6; 286-08-8; 558-37-2 (3,3-Dimethyl-1-butene); 766-29-0; 931-64-6 Role: RCT (Reactant), RACT (Reactant or reagent) (transmetalation of, by pentylsodium, effect of activators on)
Laboratories
LSCO
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
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Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2006-03-03