The super-basic butyllithium/potassium tert-butoxide mixture and other LICKOR reagents
1984
Résumé
The reactivity pattern of the butyllithium/potassium tert-butoxide mixt. with cumene differs significantly from that of BuK and thus disproves the claimed identity of these two reagents. [on SciFinder (R)]
Détails
Titre
The super-basic butyllithium/potassium tert-butoxide mixture and other LICKOR reagents
Auteur(s)
Schlosser, Manfred ; Strunk, Sven
Publié dans
Tetrahedron Letters
Volume
25
Numéro
7
Pages
741-4
Date
1984
ISSN
0040-4039
Mots-clés (libres)
Regiochemistry (for metalation of cumene using LICKOR reagents); Metalation (of cumene by LICKOR reagents); Lithiation (of cumene; by butyllithium-potassium tert-butoxide mixts.); butyllithium potassium butoxide mixt; LICKOR reagent regiochemistry; lithium butyl potassium butoxide mixt; lithiation reagent regiochemistry
Note
CAN 101:7226
29-2
Organometallic and Organometalloidal Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in English.
6231-20-5; 53127-82-5 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation by, of cumene); 98-82-8 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation of, LICKOR reagents for); 865-47-4 Role: RCT (Reactant), RACT (Reactant or reagent) (mixts. with butyllithium, as lithiating reagent); 16872-93-8; 20484-37-1; 78278-74-7; 90527-23-4 Role: RCT (Reactant), RACT (Reactant or reagent) (mixts. with butyllithium, for metalation of cumene); 594-19-4; 598-30-1; 917-54-4 Role: RCT (Reactant), RACT (Reactant or reagent) (mixts. with potassium alkoxides, for metalation of cumene); 109-72-8 Role: USES (Uses) (mixts. with potassium tert-butoxide, as lithiating reagent); 27303-98-6 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with butyllithium, ppt. from)
29-2
Organometallic and Organometalloidal Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in English.
6231-20-5; 53127-82-5 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation by, of cumene); 98-82-8 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation of, LICKOR reagents for); 865-47-4 Role: RCT (Reactant), RACT (Reactant or reagent) (mixts. with butyllithium, as lithiating reagent); 16872-93-8; 20484-37-1; 78278-74-7; 90527-23-4 Role: RCT (Reactant), RACT (Reactant or reagent) (mixts. with butyllithium, for metalation of cumene); 594-19-4; 598-30-1; 917-54-4 Role: RCT (Reactant), RACT (Reactant or reagent) (mixts. with potassium alkoxides, for metalation of cumene); 109-72-8 Role: USES (Uses) (mixts. with potassium tert-butoxide, as lithiating reagent); 27303-98-6 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with butyllithium, ppt. from)
Laboratoires
LSCO
Le document apparaît dans
Production scientifique et compétences > SB - Faculté des sciences de base > SB Archives > LSCO - Laboratoire de synthèse organique et catalyse
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Date de création de la notice
2006-03-03