The super-basic butyllithium/potassium tert-butoxide mixture and other LICKOR reagents

The reactivity pattern of the butyllithium/potassium tert-butoxide mixt. with cumene differs significantly from that of BuK and thus disproves the claimed identity of these two reagents. [on SciFinder (R)]


Published in:
Tetrahedron Letters, 25, 7, 741-4
Year:
1984
Keywords:
Note:
CAN 101:7226
29-2
Organometallic and Organometalloidal Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
0040-4039
written in English.
6231-20-5; 53127-82-5 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation by, of cumene); 98-82-8 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation of, LICKOR reagents for); 865-47-4 Role: RCT (Reactant), RACT (Reactant or reagent) (mixts. with butyllithium, as lithiating reagent); 16872-93-8; 20484-37-1; 78278-74-7; 90527-23-4 Role: RCT (Reactant), RACT (Reactant or reagent) (mixts. with butyllithium, for metalation of cumene); 594-19-4; 598-30-1; 917-54-4 Role: RCT (Reactant), RACT (Reactant or reagent) (mixts. with potassium alkoxides, for metalation of cumene); 109-72-8 Role: USES (Uses) (mixts. with potassium tert-butoxide, as lithiating reagent); 27303-98-6 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with butyllithium, ppt. from)
Laboratories:




 Record created 2006-03-03, last modified 2018-01-27


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