Alcoholate Clusters ("Aggregates") and Their Role in Alkyne Forming Elimination Reactions
Schlosser, Manfred; Tran Dinh, An
1981

Abstract

Kinetic data for the dehydrochlorination of (E)- and (Z)-MeCH:CClC.tplbond.CCMe3 by KOCMe3 (I) in different solvents suggested that I assocs. participated in a push-pull, conveyor-belt mechanism. MeC.tplbond.CC.tplbond.CCMe3 was the only product from both olefin isomers. [on SciFinder (R)]

Details

Title Alcoholate Clusters ("Aggregates") and Their Role in Alkyne Forming Elimination Reactions
Author(s) Schlosser, Manfred ; Tran Dinh, An
Published in Angewandte Chemie, International Edition
Volume 20
Pages 1039-1040
Date 1981
Keywords
Note CAN 96:51537 22-4 Physical Organic Chemistry Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz. Journal 0044-8249 written in German. 79816-87-8; 79816-88-9 Role: RCT (Reactant), RACT (Reactant or reagent) (dehydrochlorination of, by tert-butoxide, aggregation of base in); 821-73-8P Role: FORM (Formation, nonpreparative), PREP (Preparation) (formation of, kinetics of)
DOI https://doi.org/10.1002/anie.198110391
Laboratories LSCO
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2006-03-03

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