Alcoholate Clusters ("Aggregates") and Their Role in Alkyne Forming Elimination Reactions

Kinetic data for the dehydrochlorination of (E)- and (Z)-MeCH:CClC.tplbond.CCMe3 by KOCMe3 (I) in different solvents suggested that I assocs. participated in a push-pull, conveyor-belt mechanism. MeC.tplbond.CC.tplbond.CCMe3 was the only product from both olefin isomers. [on SciFinder (R)]


Published in:
Angewandte Chemie, International Edition, 20, 1039-1040
Year:
1981
Keywords:
Note:
CAN 96:51537 22-4 Physical Organic Chemistry Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz. Journal 0044-8249 written in German. 79816-87-8; 79816-88-9 Role: RCT (Reactant), RACT (Reactant or reagent) (dehydrochlorination of, by tert-butoxide, aggregation of base in); 821-73-8P Role: FORM (Formation, nonpreparative), PREP (Preparation) (formation of, kinetics of)
Laboratories:




 Record created 2006-03-03, last modified 2018-01-27


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)