Allylic Compounds of Magnesium, Lithium and Potassium : sigma- oder pi-Structures ?

The s- vs. p-character of title allylmetal compds. was studied via 13C NMR of R2CR1:CRCH2N (R = H, Me2CH, Me3C, R1 = R2 = H; R = R1 = H, R2 = Me; R = H, R1 = R2 = Me; M = Li, K, MgBr) and of deuterated derivs. [on SciFinder (R)]


Published in:
Angewandte Chemie, International Edition, 19, 487-488
Year:
1980
Keywords:
Note:
CAN 93:203793 22-8 Physical Organic Chemistry Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz. Journal 0044-8249 written in German. 1730-25-2; 3052-45-7; 6088-87-5; 7329-38-6; 16327-44-9; 50585-10-9; 63847-45-0; 73891-64-2; 73891-65-3; 73891-66-4; 73891-67-5; 73891-68-6 Role: PRP (Properties) (structure of, carbon-13 NMR and)
Laboratories:




 Record created 2006-03-03, last modified 2018-01-27


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