Abstract
The acetolysis of 1-chloro-1-fluorocyclopropanes I [R = Me, (CH2)3OAc] with AgOAc in Ac2O contg. BF3 gave the resp. RCMe(OAc)CF:CH2 (II) initially, and the II eventually rearranged to the more stable RCMe:CFCH2OAc. [on SciFinder (R)]
Details
Title
Solvolyse de Chlorofluorocyclopropanes
Author(s)
Bessiere, Vyonne ; Schlosser, Manfred
Published in
Helvetica Chimica Acta
Volume
59
Issue
3
Pages
969-978
Date
1976
ISSN
0018-019X
Keywords
Ring cleavage (in acetolysis of geminal chlorofluorocyclopropanes); Allylic rearrangement (of 1; 1-disubstituted 2-fluoroallyl acetates); Acetolysis (of geminal chlorofluorocyclopropanes; ring cleavage in); cyclopropane geminal chlorofluoro acetolysis; chlorofluorocyclopropane geminal acetolysis; rearrangement allylic fluoroallyl acetate; ring cleavage acetolysis chlorofluorocyclopropane
Note
CAN 85:123394
24-2
Alicyclic Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in French.
1891-96-9; 52633-87-1 Role: RCT (Reactant), RACT (Reactant or reagent) (acetolysis of, ring cleavage in); 60386-33-6 Role: RCT (Reactant), RACT (Reactant or reagent) (hydrolysis of); 60386-30-3P; 60386-31-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and allylic rearrangement of); 2356-08-3P; 7569-36-0P; 52633-85-9P; 52633-91-7P; 58715-39-2P; 60386-32-5P; 60386-34-7P; 60386-35-8P; 60386-36-9P; 60386-37-0P; 60386-38-1P; 60386-39-2P; 60386-40-5P; 60386-41-6P; 60386-42-7P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
24-2
Alicyclic Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in French.
1891-96-9; 52633-87-1 Role: RCT (Reactant), RACT (Reactant or reagent) (acetolysis of, ring cleavage in); 60386-33-6 Role: RCT (Reactant), RACT (Reactant or reagent) (hydrolysis of); 60386-30-3P; 60386-31-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and allylic rearrangement of); 2356-08-3P; 7569-36-0P; 52633-85-9P; 52633-91-7P; 58715-39-2P; 60386-32-5P; 60386-34-7P; 60386-35-8P; 60386-36-9P; 60386-37-0P; 60386-38-1P; 60386-39-2P; 60386-40-5P; 60386-41-6P; 60386-42-7P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
Laboratories
LSCO
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2006-03-03