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Metallierung allylständiger Methylen- und Methin-Gruppen

Metalation of cyclohexene by Me3SiCH2K, then treatment with ethylene oxide gave 83% 2-cyclohexene-1-ethanol. Similarly, Me2CHCH:CH2 gave 37% Me2C:CH(CH2)3OH and 28% CH2:CHCMe2CH2CH2OH. [on SciFinder (R)]

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