Metallierung allylständiger Methylen- und Methin-Gruppen

Metalation of cyclohexene by Me3SiCH2K, then treatment with ethylene oxide gave 83% 2-cyclohexene-1-ethanol. Similarly, Me2CHCH:CH2 gave 37% Me2C:CH(CH2)3OH and 28% CH2:CHCMe2CH2CH2OH. [on SciFinder (R)]


Published in:
Synthesis, 5, 328-9
Year:
1975
Keywords:
Note:
CAN 83:58913
29-2
Organometallic and Organometalloidal Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
0039-7881
written in German.
110-83-8 Role: RCT (Reactant), RACT (Reactant or reagent) (allylic metalation of, by [(trimethylsilyl)methyl]potassium); 53127-82-5 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation of cyclohexene and 3-methyl-1-butene by); 563-45-1 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation of, by [(trimethylsilyl)methyl]potassium); 16452-34-9P; 42272-94-6P; 53589-56-3P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
Laboratories:




 Record created 2006-03-03, last modified 2018-01-27


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