Insertion of a Carbon Atom into Olefinic Double Bonds : Synthesis of Fluorodienes and Fluoroalkenes

Reaction of chlorofluorocarbene with CH2:CMeCH2Cl gave I (R = Cl), which was treated with NaI to give I (R = I). Reaction of this with Zn gave CH2:CFCMe:CH2, which, on treatment with Br, gave BrCH2CF:CMeCH2Br. [on SciFinder (R)]


Published in:
Angewandte Chemie, International Edition, 14, 365-366
Year:
1975
Keywords:
Note:
CAN 83:192464 23-3 Aliphatic Compounds Inst. Chem. Org.,Univ. Lausanne,Lausanne,Switz. Journal 0044-8249 written in German. 1691-88-9 Role: RCT (Reactant), RACT (Reactant or reagent) (cycloaddn. reaction with methylallyl chloride); 338-68-1P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and bromination of); 40841-57-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction with iodide); 54699-04-6P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and reaction with zinc); 54699-05-7P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 563-47-3 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction with chlorofluoromethylene)
Laboratories:




 Record created 2006-03-03, last modified 2018-12-03


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