Journal article

Insertion of a Carbon Atom into Olefinic Double Bonds : Synthesis of Fluorodienes and Fluoroalkenes

Reaction of chlorofluorocarbene with CH2:CMeCH2Cl gave I (R = Cl), which was treated with NaI to give I (R = I). Reaction of this with Zn gave CH2:CFCMe:CH2, which, on treatment with Br, gave BrCH2CF:CMeCH2Br. [on SciFinder (R)]


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