Prescriptions and ingredients for controlled carbon-carbon bond formation with organometallic reagents
1975
Abstract
Merits and drawbacks of known C-C linking procedures, such as condensation, addn., and isomerization reactions, are outlined. Two novel methods are discussed in more detail: the Cu-catalyzed alkylation of Grignard reagents, and reactions with allylpotassium compd. Both the methods efficiently give satd., usatd., and functionally substituted hydrocarbons; the methods provide regio- and stereoselective control of olefin synthesis. [on SciFinder (R)]
Details
Title
Prescriptions and ingredients for controlled carbon-carbon bond formation with organometallic reagents
Author(s)
Schlosser, Manfred
Published in
New Synthetic Methods
Volume
2
Pages
1-15
Date
1975
Keywords
Grignard's reagents Role: RCT (Reactant); RACT (Reactant or reagent) (alkylation of; copper-catalyzed); Addition reaction; Condensation reaction; Isomerization (carbon-carbon bond formation via; use of organometallic reagents for); Alkylation catalysts; organometallic reagent; org synthesis; condensation organometallic reagent; addn organometallic reagent; isomerization organometallic reagent; Grignard alkylation copper; allylpotassium reaction; hydrocarbon; olefin
Note
CAN 86:170085 21-1 General Organic Chemistry Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz. Conference written in English. 1003-64-1 Role: RCT (Reactant), RACT (Reactant or reagent) (formation of potassium deriv. from); 62748-36-1P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and isomerization of); 62748-35-0P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and methylation of); 62748-37-2P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and photolysis of); 2129-93-3P; 21623-78-9P; 34214-00-1P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
Laboratories
LSCO
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Work produced at EPFL
Book chapters
Published
Work produced at EPFL
Book chapters
Published
Record creation date
2006-03-03