Silberion-induzierte Ringöffnung von Chlorofluorocyclopropanen

MeCR:CFCH2OH (R = Me, Pr, (CH2)3OAc) were prepd. in 53-60% yield by ring-cleavage of the cyclopropanes I with AgOAc-AgBF4 to give 50-64% MeCR:CFCH2OAc followed by hydrolysis. The isomeric acetates were easily sepd. by gas chromatog. [on SciFinder (R)]


Published in:
Synthesis, 2, 115-16
Year:
1974
Keywords:
Note:
CAN 81:25168
24-7
Alicyclic Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
0039-7881
written in German.
563-63-3; 14104-20-2 Role: RCT (Reactant), RACT (Reactant or reagent) (cyclopropane ring cleavage by); 52633-85-9P; 52633-88-2P; 52633-89-3P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and hydrolysis of); 2356-08-3P; 52633-90-6P; 52633-91-7P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 1891-96-9 Role: RCT (Reactant), RACT (Reactant or reagent) (ring cleavage of, silver-induced); 52633-86-0; 52633-87-1 Role: RCT (Reactant), RACT (Reactant or reagent) (ring-cleavage of, silver-induced)
Laboratories:




 Record created 2006-03-03, last modified 2018-12-03


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