Die Photofragmentierung eines Phosphor-Ylids
Short-wavelength irradn. of Ph3P+C-Me2 gave C6H6 and a resinous compd. Long-wavelength irradn. of Ph3P+C-Me2 gave mainly Ph3P and Me2C:CMe2 with some Me2CHCHMe2, MeCH:CH2, and, with Me2CHCHMe2 as solvent, traces of (Me2CH)2CMe2 and Me2CHCHMeCH2CHMe2. the reaction proceeded via .CMe2.PPh3. [on SciFinder (R)]
Physical Organic Chemistry
Fachbereich Org. Chem.,Univ. Saarlandes,Saarbruecken,Fed. Rep. Ger.
written in German.
16666-80-1; 20262-14-0 Role: RCT (Reactant), RACT (Reactant or reagent) (photolysis of, mechanism of)
Record created on 2006-03-03, modified on 2016-08-08