Metallbindungsphänomene : Alkoholat-Aggregate als unmittelbare Teilnehmer an Eliminierungsreaktionen
1973
Abstract
Kinetic data were obtained for the dehydrohalogenation in C6H6 and PhMe of vic-dihaloalkanes and vic-dihalocycloalkanes in the presence of KOCMe3. The mechanism involved oligomeric alc. aggregates which affected the stereochem. of the reaction. [on SciFinder (R)]
Details
Title
Metallbindungsphänomene : Alkoholat-Aggregate als unmittelbare Teilnehmer an Eliminierungsreaktionen
Author(s)
Schlosser, Manfred ; Jan, Gerald ; Byrne, Edeline ; Sicher, Jiri
Published in
Helvetica Chimica Acta
Volume
56
Issue
5
Pages
1630-7
Date
1973
ISSN
0018-019X
Keywords
Kinetics of dehydrochlorination (of 1; 2-dichlorocyclodecane and 4; 5-dichlorooctanes by reaction with potassium tert-butoxide in benzene or toluene); Dehydrochlorination (of 1; 2-dichlorocyclodecane and 4; 5-dichlorooctanes; by reaction with potassium tert; dehydrohalogenation dihaloalkane alcoholate stereochem; alkane dihalo dehydrohalogenation alcoholate; cycloalkane dihalo dehydrohalogenation alcoholate; haloalkane dehydrohalogenation alcoholate stereochem
Note
CAN 80:47070
22-3
Physical Organic Chemistry
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in German.
692-70-6 Role: RCT (Reactant), RACT (Reactant or reagent) (bromination of); 865-47-4 Role: PRP (Properties) (dehydrohalogenation of vic-dihaloalkanes and -cycloalkanes by reaction with, kinetics and mechanism of); 286-94-2 Role: RCT (Reactant), RACT (Reactant or reagent) (hydrochlorination of); 40084-93-3P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and kinetics of dehydrobromination of); 29523-05-5P; 51149-23-6P; 51149-24-7P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and kinetics of dehydrochlorination of); 7321-48-4P; 10124-70-6P; 40084-92-2P; 51149-22-5P; 51149-25-8P; 51149-26-9P; 51776-94-4P; 51776-95-5P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
22-3
Physical Organic Chemistry
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in German.
692-70-6 Role: RCT (Reactant), RACT (Reactant or reagent) (bromination of); 865-47-4 Role: PRP (Properties) (dehydrohalogenation of vic-dihaloalkanes and -cycloalkanes by reaction with, kinetics and mechanism of); 286-94-2 Role: RCT (Reactant), RACT (Reactant or reagent) (hydrochlorination of); 40084-93-3P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and kinetics of dehydrobromination of); 29523-05-5P; 51149-23-6P; 51149-24-7P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and kinetics of dehydrochlorination of); 7321-48-4P; 10124-70-6P; 40084-92-2P; 51149-22-5P; 51149-25-8P; 51149-26-9P; 51776-94-4P; 51776-95-5P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
Laboratories
LSCO
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2006-03-03