Metallbindungsphänomene : Alkoholat-Aggregate als unmittelbare Teilnehmer an Eliminierungsreaktionen

Kinetic data were obtained for the dehydrohalogenation in C6H6 and PhMe of vic-dihaloalkanes and vic-dihalocycloalkanes in the presence of KOCMe3. The mechanism involved oligomeric alc. aggregates which affected the stereochem. of the reaction. [on SciFinder (R)]


Published in:
Helvetica Chimica Acta, 56, 5, 1630-7
Year:
1973
Keywords:
Note:
CAN 80:47070
22-3
Physical Organic Chemistry
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
0018-019X
written in German.
692-70-6 Role: RCT (Reactant), RACT (Reactant or reagent) (bromination of); 865-47-4 Role: PRP (Properties) (dehydrohalogenation of vic-dihaloalkanes and -cycloalkanes by reaction with, kinetics and mechanism of); 286-94-2 Role: RCT (Reactant), RACT (Reactant or reagent) (hydrochlorination of); 40084-93-3P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and kinetics of dehydrobromination of); 29523-05-5P; 51149-23-6P; 51149-24-7P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and kinetics of dehydrochlorination of); 7321-48-4P; 10124-70-6P; 40084-92-2P; 51149-22-5P; 51149-25-8P; 51149-26-9P; 51776-94-4P; 51776-95-5P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
Laboratories:




 Record created 2006-03-03, last modified 2018-01-27


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