Journal article

a-Substitution plus carbonyl olefination via b-oxido phosphorus ylids (S.C.O.O.P.Y.-reactions) scope and stereoselectivity

Consecutive treatment of HOCH2CH2P+Ph3 Br- with BuLi, BzH, BuLi, and H2O afforded trans-PhCH:CHCH2OH in 95% isomeric purity and PhCH(OH)CH:CH2. The stereospecificity of the S.C.O.O.P.Y.-reactions (Schlosser, M. and Christmann, F. K., 1969) is discussed. [on SciFinder (R)]


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