Abstract
syn-Substituted cyclopropanes (syn-I) (R, R1, and X are above the plane) and anti-I (X is below the plane) are prepd. from R1R3C:CRR2 and :CHF (from Br2CHF and BuLi). syn- and anti-I(X = Cl) are also prepd.; the syn-anti ratios for I(X = F and X = Cl) are similar. The formation of syn-transition states is discussed. [on SciFinder (R)]
Details
Title
Monofluorocarbene and its syn-anti selectivity
Author(s)
Schlosser, Manfred ; Heinz, G.
Published in
Angewandte Chemie, International Edition
Volume
7
Issue
10
Pages
820-821
Date
1968
Keywords
Note
CAN 70:11161 24 Alicyclic Compounds Univ. Heidelberg,Heidelberg,Fed. Rep. Ger. Journal 0570-0833 written in English. 13453-52-6 Role: PROC (Process) (addn. of, to olefins)
Laboratories
LSCO
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2006-03-03