Monofluorocarbene and its syn-anti selectivity

syn-Substituted cyclopropanes (syn-I) (R, R1, and X are above the plane) and anti-I (X is below the plane) are prepd. from R1R3C:CRR2 and :CHF (from Br2CHF and BuLi). syn- and anti-I(X = Cl) are also prepd.; the syn-anti ratios for I(X = F and X = Cl) are similar. The formation of syn-transition states is discussed. [on SciFinder (R)]


Published in:
Angewandte Chemie, International Edition, 7, 10, 820-821
Year:
1968
Keywords:
Note:
CAN 70:11161 24 Alicyclic Compounds Univ. Heidelberg,Heidelberg,Fed. Rep. Ger. Journal 0570-0833 written in English. 13453-52-6 Role: PROC (Process) (addn. of, to olefins)
Laboratories:




 Record created 2006-03-03, last modified 2018-01-27


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