Infoscience

Journal article

Der Einfluß von Stereochemie und Substituenten auf die Reaktivität von Vinylhalogeniden

RCH:CHCl (R = Ph, o-, m-, and p-MeC6H4, 2,4,6-Me3C6H2, PhCH2, PhCH:CH, PhC.tplbond.C, a-furyl, etc.) reacted with PhLi to give RC.tplbond.CLi with the intermediate formation of RCH:CLiCl. cis- RCH:CHCl was less reactive than trans-RCH:CHCl due to steric effects. The rate of the reaction between RCH:CHCl and PhLi was lower for electron-rich R, as compared to electron-poor R. [on SciFinder (R)]

    Keywords: Isotopic effects (in b-chlorostyrene reaction with phenyllithium ; by deuterium); Kinetics (of b-chlorostyrenes with phenyllithium) ; BASE INDUCED ELIMINATION; VINYL CHLORIDE REACTIVITY; ELIMINATION BASE INDUCED

    Note:

    CAN 68:38801 22 Physical Organic Chemistry Univ. Heidelberg,Heidelberg,Fed. Rep. Ger. Journal 0009-2940 written in German. 7782-39-0 Role: PRP (Properties) (isotopic effect of, in b-chlorostyrene reaction with phenyllithium); 705-28-2P; 766-82-5P; 766-83-6P; 766-97-2P; 768-60-5P; 768-70-7P; 873-73-4P; 2561-17-3P; 18649-64-4P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 4110-77-4; 4604-28-8; 18684-74-7; 18684-75-8; 18684-76-9; 18684-77-0; 18684-78-1; 18684-79-2; 18684-80-5; 18684-81-6; 18684-82-7; 18684-83-8; 18684-84-9; 18684-85-0; 18684-86-1; 18684-87-2; 18684-88-3; 18684-89-4; 18684-90-7; 18684-91-8; 18684-92-9; 18684-93-0; 18684-94-1; 18684-95-2; 18684-96-3; 18684-97-4; 18684-98-5; 18684-99-6; 18685-00-2; 18685-01-3; 18685-02-4; 18685-03-5 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with phenyllithium, kinetics of); 591-51-5 Role: RCT (Reactant), RACT (Reactant or reagent) (reaction of, with b-chlorostyrenes, kinetics of)

    Reference

    • LSCO-ARTICLE-1967-001

    Record created on 2006-03-03, modified on 2016-08-08

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