Nucleophilic ligand exchange by phosphoranes
Schlosser, Manfred; Kadibelban, Taufik; Steinhoff, G.
1966

Abstract

The org. groups of pentaorganylphosphorus compds. were found to undergo nucleophilic exchange with organolithium reagents. If an ethereal soln. of pentaphenylphosphorus is treated at room temp. with, e.g., 5 equivs. p-tolyllithium, the tetraarylphosphonium salts obtained by subsequent action of acids shows the ir bands of a tolyl group. [on SciFinder (R)]

Details

Title Nucleophilic ligand exchange by phosphoranes
Author(s) Schlosser, Manfred ; Kadibelban, Taufik ; Steinhoff, G.
Published in Angewandte Chemie, International Edition
Volume 5
Issue 11
Pages 968-969
Date 1966
Keywords
Note CAN 66:18745 29 Organometallic and Organometalloidal Compounds Univ. Heidelberg,Heidelberg,Germany. Journal 0570-0833 written in English. 13769-19-2D (Phosphorane) Role: RCT (Reactant), RACT (Reactant or reagent) (exchange reactions with org. lithium compds.); 1779-50-6P; 1779-51-7P; 3317-28-0P; 13270-71-8P; 13270-72-9P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of); 7439-93-2D (Lithium) Role: RCT (Reactant), RACT (Reactant or reagent) (reaction with phosphoranes)
DOI https://doi.org/10.1002/anie.196609682
Laboratories LSCO
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSCO - Laboratory of Organic Synthesis and Catalysis
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2006-03-03

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