Journal article

Nucleophilic ligand exchange by phosphoranes

The org. groups of pentaorganylphosphorus compds. were found to undergo nucleophilic exchange with organolithium reagents. If an ethereal soln. of pentaphenylphosphorus is treated at room temp. with, e.g., 5 equivs. p-tolyllithium, the tetraarylphosphonium salts obtained by subsequent action of acids shows the ir bands of a tolyl group. [on SciFinder (R)]


  • There is no available fulltext. Please contact the lab or the authors.

Related material