Résumé

A symposium report on the construction of regioselectively addressable functionalized template (RAFT) mols., e.g. I [R = Me3CO2C (Boc); R1 = H2C:CHCH2O2C (Alloc)], as conformationally stable cyclopeptide scaffolds in which lysine side chains point to opposite side of the template backbone. Chimeric mol. I [R = H-His, R1 = S(CH2)10CO] was prepd. and complexed to Zn2+, Cu2+, and attached to a gold surface. [on SciFinder (R)]

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