000080914 001__ 80914
000080914 005__ 20181203020258.0
000080914 0247_ $$2doi$$a10.1002/1521-3773(20020315)41:6<979::AID-ANIE979>3.0.CO;2-E
000080914 037__ $$aARTICLE
000080914 245__ $$aThe mechanism of catalytic enantioselective fluorination: Computational and experimental studies
000080914 269__ $$a2002
000080914 260__ $$c2002
000080914 336__ $$aJournal Articles
000080914 520__ $$aA parallel orientation between the coordinated substrate enolate and a face-on naphthyl group of the TAD-DOL ligand control the stereochem. outcome of the Ti-catalyzed asym. fluorination of 1,3-dicarbonyl compds. with 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octanetriethylenediamine (F-TEDA). D. functional theory based quantum-mech. mol. mech. calcns. also disclose the fluorine-transfer step as occurring by a single-electron transfer. [on SciFinder (R)]
000080914 700__ $$0241329$$g153495$$aPiana, Stefano
000080914 700__ $$aDevillers, Ingrid
000080914 700__ $$aTogni, Antonio
000080914 700__ $$aRothlisberger, Ursula$$g150117$$0241350
000080914 773__ $$j41$$tAngewandte Chemie, International Edition$$k6$$q979-982
000080914 909C0 $$xU2$$0252093$$pLCBC
000080914 909CO $$pSB$$particle$$ooai:infoscience.tind.io:80914
000080914 937__ $$aLCBC-ARTICLE-2002-005
000080914 970__ $$a16/LCBC
000080914 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000080914 980__ $$aARTICLE