Isolation of a highly persistent diphosphanyl radical: the phosphorus analogue of a hydrazyl
2001
Abstract
Herein is reported the synthesis and characterization of a [RR1P-PR]-type radical, (I) (R = 2,4,6-tBu3C6H2; R' = CH3). I is stable in the solid state at temps. below -30 Deg. Suitable crystals of I were unobtainable, but a combination of EPR expts. and theor. methods allowed for unambiguous detn. of its structure. [on SciFinder (R)]
Details
Title
Isolation of a highly persistent diphosphanyl radical: the phosphorus analogue of a hydrazyl
Author(s)
Loss, Sandra ; Magistrato, Alessandra ; Cataldo, Laurent ; Hoffmann, Stefan ; Geoffroy, Michel ; Rothlisberger, Ursula ; Grutzmacher, Hansjorg
Published in
Angewandte Chemie, International Edition
Volume
40
Issue
4
Pages
723-726
Date
2001
Laboratories
LCBC
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCBC - Laboratory of Computational Chemistry and Biochemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2006-02-27