000080501 001__ 80501
000080501 005__ 20180317092948.0
000080501 0247_ $$2doi$$a10.1016/0009-2614(94)87051-9
000080501 037__ $$aARTICLE
000080501 245__ $$aExperimental evidence to Rydbergization of antibonding molecular orbitals
000080501 269__ $$a1994
000080501 260__ $$c1994
000080501 336__ $$aJournal Articles
000080501 520__ $$aExptl. evidence is presented for the process of MO Rydbergization postulated by Mulliken, whereby an antibonding orbital continuously changes its character from predominantly Rydberg to predominantly valence on its way to dissocn. By matrix-isolation spectroscopy of the ~A1B1 state of H2O in Ar and Kr matrixes and in ice, the authors show that the absorption threshold behaves like a valence transition while the max. has a behavior typical of Rydberg transitions in condensed matter, in agreement with the predicted changing character of the state. [on SciFinder (R)]
000080501 700__ $$0240045$$aChergui, M.$$g122830
000080501 700__ $$aSchwentner, N.
000080501 773__ $$j219$$k3-4$$q237-42$$tChemical Physics Letters
000080501 909CO $$ooai:infoscience.tind.io:80501$$particle$$pSB
000080501 909C0 $$0252026$$pLSU$$xU10862
000080501 937__ $$aLSU-ARTICLE-1994-004
000080501 970__ $$a9/LSU
000080501 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000080501 980__ $$aARTICLE