Journal article

Accurate measurement of residual dipolar couplings in anisotropic phase

The detn. of residual dipolar couplings (RDCs) by quant. J spectroscopy methods such as heteronuclear single quantum correlation with phase encoded coupling (HSQC-PEC) is prone to systematic errors that may be caused by differential attenuation during the conversion of orthogonal d. operator components into observable terms. The attenuation may be caused by miscalibration of r.f. pulses and by relaxation effects. A simple method is presented that allows one to remove most of these systematic errors without losses in sensitivity or resoln. [on SciFinder (R)]


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