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research article
Average Liouvillian theory revisited: cross-correlated relaxation between chemical shift anisotropy and dipolar couplings in the rotating frame in nuclear magnetic resonance
1999
A review is given of the math. foundations of av. Liouvillian theory and examples are provided of av. Liouvillian expressions derived for sequences in NMR which possess temporal symmetry or antisymmetry. The utility of this approach is demonstrated in the design of pulse sequences to measure the effect of cross-correlation between chem. shift anisotropy and dipolar couplings on relaxation rates in biomols. Exptl. verification of the theory is carried out on a 15N labeled sample of ubiquitin. [on SciFinder (R)]
Type
research article
Authors
Publication date
1999
Published in
Volume
96
Issue
8
Start page
1281
End page
1288
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
February 22, 2006
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