000080215 001__ 80215
000080215 005__ 20180317093601.0
000080215 0247_ $$2doi$$a10.1021/ja00369a027
000080215 037__ $$aARTICLE
000080215 245__ $$aDirect determination of rate constants of slow dynamic processes by two-dimensional \"accordion\" spectroscopy in nuclear magnetic resonance
000080215 269__ $$a1982
000080215 260__ $$c1982
000080215 336__ $$aJournal Articles
000080215 520__ $$aA novel class of NMR expts., based on the systematic variation of 3 time variables, permits both the identification of exchange networks and the direct measurement of the corresponding rate consts. in soln. Linear combinations of cross sections taken from 2 dimensional spectra allow a straightforward anal. of nonexponential recovery behavior by identifying normal modes. The line widths of the resulting Lorentzian line shapes provide a direct measure of the rate consts. of various dynamic processes, such as chem. exchange, transient Overhauser effects, and spin-lattice relaxation. [on SciFinder (R)]
000080215 700__ $$0243177$$aBodenhausen, Geoffrey$$g122795
000080215 700__ $$aErnst, R. R.
000080215 773__ $$j104$$k5$$q1304-9$$tJournal of the American Chemical Society
000080215 909CO $$ooai:infoscience.tind.io:80215$$particle$$pSB
000080215 909C0 $$0252152$$pLRMB$$xU10098
000080215 937__ $$aLRMB-ARTICLE-1982-003
000080215 970__ $$a58/LRMB
000080215 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000080215 980__ $$aARTICLE