Electrochemical preparation of peroxodisulfuric acid using boron doped diamond thin film electrodes

The authors have studied the electrochem. oxidn. of H2SO4 on B-doped synthetic diamond electrodes (BDD) obtained by hot filament CVD on p-Si. High current efficiency for H2SO4 oxidn. to peroxodisulfuric acid can be achieved in concd. H2SO4 (>2M) at moderate temps. (8-10 Deg). The main side reaction is oxygen evolution. Small amts. of peroxomonosulfuric acid (Caro's acid) also were detected. A reaction mechanism involving hydroxyl radicals, HSO4- and undissociated H2SO4 is proposed. According to this mechanism electrogenerated hydroxyl radicals at the BDD anode react with HSO4- and H2SO4 giving peroxodisulfate. [on SciFinder (R)]

Publié dans:
Electrochimica Acta, 48, 4, 431-436
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 Notice créée le 2006-02-22, modifiée le 2018-12-03

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