000079875 001__ 79875
000079875 005__ 20181203020234.0
000079875 02470 $$2DAR$$a991
000079875 02470 $$2ISI$$a000179412900008
000079875 037__ $$aARTICLE
000079875 245__ $$aElectrochemical oxidation of phenol at boron-doped diamond electrode. Application to electro-organic synthesis and wastewater treatment
000079875 260__ $$c2002
000079875 269__ $$a2002
000079875 336__ $$aJournal Articles
000079875 520__ $$aThe electrochem. behavior of a synthetic B-doped diamond thin film electrode (BDD) was studied in acid media contg. phenol using cyclic voltammetry and bulk electrolysis. In the potential region of H2O stability direct electron transfers can occur on BDD surface resulting in electrode fouling due to the formation of a polymeric film on its surface. During electrolysis in the potential region of oxygen evolution, complex oxidn. reactions can take place due to electrogenerated hydroxyl radicals. Electrode fouling is inhibited under these conditions. Depending on the exptl. conditions, the electrogenerated hydroxyl radicals can lead to the combustion of phenol or to the selective oxidn. of phenol to benzoquinone. The exptl. results also were compared to a theor. model that permits the prediction of the evolution with time of phenol concn., during its combustion, or during its selective oxidn. to benzoquinone. [on SciFinder (R)]
000079875 700__ $$aPanizza, Marco
000079875 700__ $$0241560$$g102665$$aMichaud, Pierre-Alain
000079875 700__ $$aIniesta, Jesus
000079875 700__ $$g104807$$aComninellis, Christos$$0240416
000079875 700__ $$aCerisola, Giacomo
000079875 773__ $$j92$$tAnnali di Chimica$$k10$$q995-1006
000079875 909C0 $$0252005$$pGGEC$$xU10173
000079875 909CO $$particle$$ooai:infoscience.tind.io:79875
000079875 937__ $$aGGEC-ARTICLE-2002-005
000079875 970__ $$a21/GGEC
000079875 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000079875 980__ $$aARTICLE