Reactions of organic compounds in aqueous hydrofluoric acid
Comninellis, Ch; Javet, Ph; Plattner, E.
1975

Abstract

Anthraquinone with HNO3 or N2O4 in 80-98% HF gave nitroanthraquinone. The presence of H2O enabled the reaction temp. of 30-40 Deg to be maintained without external pressure and made the sepn. of the 2 isomers easier. Me(CH2)7SH with NO2 and HF gave Me(CH2)7SO2F. The yield varied with the concn. of HF; no product was obtained with an HF concn. of <40%. [on SciFinder (R)]

Details

Title Reactions of organic compounds in aqueous hydrofluoric acid
Author(s) Comninellis, Ch ; Javet, Ph ; Plattner, E.
Published in Tetrahedron Letters
Issue 17
Pages 1429-1430
Date 1975
DOI https://doi.org/10.1016/S0040-4039(00)72160-5
Other identifier(s) View record in Web of Science
Laboratories GGEC
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > GGEC - Electrochemical Engineering Group
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2006-02-22

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