The invention relates to a method for the prodn. of salts of weakly fluorinated alcoholato complex anions according to the following formulas, M[FX(ORF)m]z (1) M[(FRO)mXFX(ORF)m]z (2) and M[(FRO)mXFX(ORF)nFX(ORF)m]z (3) (X = B, Al, Ga, In, P, As, Sb; M = monovalent or divalent cation; n = 2 for m = 3 or n = 4 for m = 5; y = 1-2). For example, Ag[FAl(OC(CF3)3)3] in 98 % yield was prepd. by the reaction of AlMe3 with HOC(CF3)3 in presence of AgBF4 in pentane. [on SciFinder (R)]
Titre
Method for the production of salts of weakly fluorinated alcoholato complex anions of main group elements
Date
2005
Editeur
(Universitaet Karlsruhe TH, Germany).
Note
Alternative title(s) :
(de) Verfahren zur herstellung von salzen schwach koordinierender aniomen, derartige salze sowie deren verwendung
(fr) Procede pour preparer des sels d'anions faiblement coordonnees, sels correspondants et leur utilisation
(en) Method for the production of salts of weakly coordinating anions, salts thereof and use thereof
Autres identifiant(s)
EPO Family ID: 34638347
Date de création de la notice
2006-02-15
