Diaquadihydroxohexakis(tri-tert-butoxysilanethiolato)octalithium(I)-toluene (1/2)

The title compd. was obtained by reaction of (tert-BuO)3SiSH with metallic Li. Crystals are monoclinic, space group P21/n, with a 13.088(3), b 27.188(5), c 17.525(4) .ANG., b 102.25(3) Deg; Z = 2, dc = 1.083; R = 0.036, Rw(F2) = 0.105 for 11,732 reflections. The mol. is located on a center of inversion. The asym. unit contains only half a mol. and one disordered toluene mol. [on SciFinder (R)]


Published in:
Acta Crystallographica Section E: Structure Reports Online, E58, 10, m569-m570
Year:
2002
Laboratories:




 Record created 2006-02-15, last modified 2018-01-27


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