Abstract
[Ag(P4)2][Al((F3C)CO2)4], with the tetrahedral P4 mol. as ligand, was prepd. and its crystal structure and Raman spectra detd. The Ag coordination is nearly planar and the calcd. mol. orbitals of the cation indicate the electronic basis for this geometry. [on SciFinder (R)]
Details
Title
Ag(P4)2+: the first homoleptic metal-phosphorus cation
Author(s)
Krossing, Ingo
Published in
Journal of the American Chemical Society
Volume
123
Issue
19
Pages
4603-4604
Date
2001
Laboratories
LCIC
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LCIC - Laboratory of Inorganic and Coordination Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2006-02-15