Ag(P4)2+: the first homoleptic metal-phosphorus cation

[Ag(P4)2][Al((F3C)CO2)4], with the tetrahedral P4 mol. as ligand, was prepd. and its crystal structure and Raman spectra detd. The Ag coordination is nearly planar and the calcd. mol. orbitals of the cation indicate the electronic basis for this geometry. [on SciFinder (R)]


Published in:
Journal of the American Chemical Society, 123, 19, 4603-4604
Year:
2001
Laboratories:




 Record created 2006-02-15, last modified 2018-01-27


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