Synthesis and X-ray Crystal Structure of (tmp)2Al-Fe(cp)(CO)2: An Alanyl-Containing Iron Complex with a Tricoordinated Aluminum Atom
Anand, B. N.; Krossing, Ingo; Noeth, Heinrich
1997

Abstract

Synthesis of the tricoordinated alanyl-contg. iron complex [(tmp)2Al-Fe(Cp)(CO)2] (1) (tmp = 2,2,6,6-tetramethylpiperidino) has been achieved in a straightforward salt elimination reaction of (tmp)2AlBr with Na[(Cp)Fe(CO)2]. 1 Crystallizes in the triclinic space group P.hivin.1 (a = 8.347(4) .ANG., b = 10.044(5) .ANG., c = 15.087(8) .ANG., a = 94.01(1) Deg, b = 91.18(1) Deg, g = 102.50(1) Deg) and is an unassocd. monomer with an Al-Fe bond length of 2.450(1) .ANG.. [on SciFinder (R)]

Details

Title Synthesis and X-ray Crystal Structure of (tmp)2Al-Fe(cp)(CO)2: An Alanyl-Containing Iron Complex with a Tricoordinated Aluminum Atom
Author(s) Anand, B. N. ; Krossing, Ingo ; Noeth, Heinrich
Published in Inorganic Chemistry
Volume 36
Issue 9
Pages 1979-1981
Date 1997
DOI https://doi.org/10.1021/ic970110f
Laboratories LCIC
Record Appears in Scientific production and competences > SB - School of Basic Sciences > SB Archives > LCIC - Laboratory of Inorganic and Coordination Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2006-02-15

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