Journal article

Synthesis and X-ray Crystal Structure of (tmp)2Al-Fe(cp)(CO)2: An Alanyl-Containing Iron Complex with a Tricoordinated Aluminum Atom

Synthesis of the tricoordinated alanyl-contg. iron complex [(tmp)2Al-Fe(Cp)(CO)2] (1) (tmp = 2,2,6,6-tetramethylpiperidino) has been achieved in a straightforward salt elimination reaction of (tmp)2AlBr with Na[(Cp)Fe(CO)2]. 1 Crystallizes in the triclinic space group P.hivin.1 (a = 8.347(4) .ANG., b = 10.044(5) .ANG., c = 15.087(8) .ANG., a = 94.01(1) Deg, b = 91.18(1) Deg, g = 102.50(1) Deg) and is an unassocd. monomer with an Al-Fe bond length of 2.450(1) .ANG.. [on SciFinder (R)]


    Record created on 2006-02-15, modified on 2016-08-08


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