Syntheses and structures of homo- and heterobimetallic, chloro-bridged complexes containing the RuCl3(AsPh3)(n) fragment (n=1,2)
Gauthier, S; Quebatte, L; Scopelliti, R; Severin, K
2004

Résumé

The reaction of [RuCl3(AsPh3)(2)(MeOH)] with the dimeric complexes [(cod)RhCl](2), [(ppy)RhCl](2) (ppy = cyclometalated 2-phenylpyridine), [(cymene)RuCl2](2) and [CP*MCl2](2) (M = Rh, Ir) has been investigated. The structure of the resulting products was shown to depend on the reaction partner. Whereas for the rhodium complexes [(cod)RhCl](2) and [(ppy)RhCl](2), heterobimetallic compounds with two halogeno-bridges were found, the reactions with the halfsandwich complexes [(cymene)RuCl2](2) and [CP*MCl2](2) gave triply bridged products with concomitant formation of mononuclear [(pi-ligand)MCl2(AsPh3)] side products. The new complexes were all characterized by single crystal X-ray analysis. (C) 2004 Elsevier B.V. All rights reserved.

Détails

Titre Syntheses and structures of homo- and heterobimetallic, chloro-bridged complexes containing the RuCl3(AsPh3)(n) fragment (n=1,2)
Auteur(s) Gauthier, S ; Quebatte, L ; Scopelliti, R ; Severin, K
Publié dans INORGANIC CHEMISTRY COMMUNICATIONS
Volume 7
Numéro 5
Pages 708-712
Date 2004
ISSN 1387-7003
DOI https://doi.org/10.1016/j.inoche.2004.03.022
Autres identifiant(s) DAR: 5203
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Laboratoires LCS
Le document apparaît dans Production scientifique et compétences > SB - Faculté des sciences de base > ISIC - Institut des sciences et ingénierie chimiques > LCS - Laboratoire de chimie supramoléculaire
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Date de création de la notice 2006-02-09

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