Stabilization of molecular LiF, LiFHF, and Na2SiF6 using metallamacrocyclic hosts

The molecular forms of LiF, LiFHF and Na2SiF6 have been stabilized using trinuclear metallamacrocyclic complexes of (cymene)Ru-II, (Cp*)Rh-III and (Cp*)Ir-III as specific receptors. The host-guest complexes were characterized by NMR spectroscopy and single crystal X-ray diffraction. Based on these results, a highly selective chemosensor for fluoride anions has been developed.


Published in:
CHIMIA, 57, 4, 190-192
Year:
2003
Other identifiers:
Laboratories:


Note: The status of this file is: EPFL only


 Record created 2006-02-09, last modified 2018-03-17

n/a:
Download fulltext
PDF

Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)