A ruthenium porphyrin catalyst immobilized in a highly cross-linked polymer

[GRAPHICS] An immobilized Ru(meso-tetraarylporphyrin) complex was shown to be a very efficient catalyst for the epoxidation of olefins. In the presence of HBr, alcohols and even alkanes could be converted to the corresponding ketones. For the latter reactions the polymeric catalyst displayed a significantly enhanced activity when compared to that of the homogeneous version.


Published in:
ORGANIC LETTERS, 3, 24, 3907-3909
Year:
2001
ISSN:
1523-7060
Laboratories:




 Record created 2006-02-09, last modified 2018-03-17


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