000059841 001__ 59841
000059841 005__ 20180317093453.0
000059841 0247_ $$2doi$$a10.1021/ic049458i
000059841 022__ $$a0020-1669
000059841 02470 $$2ISI$$a000223190300034
000059841 02470 $$2DAR$$a5521
000059841 037__ $$aARTICLE
000059841 245__ $$aAnalysis of low oxidation state transition metal clusters by laser desorption/ionization time-of-flight mass spectrometry
000059841 260__ $$c2004
000059841 269__ $$a2004
000059841 336__ $$aJournal Articles
000059841 520__ $$aA variety of homonuclear and heteronuclear transition metal carbonyl clusters have been analyzed by ultraviolet laser desorption/ionization time-of-flight mass spectrometry. The spectra were recorded in negative and positive ion modes, using both linear and reflective techniques. A range of different clusters based on different nuclearities, geometries, and ligand types, which include hydrides, phosphines, nitriles, and cyclopentadienyl ligands and naked main group atoms, were studied. These experiments have allowed us to construct a detailed picture of the technique for the analysis of transition metal carbonyl clusters and their derivatives, In general, extensive reactions are observed, cluster aggregation reactions in particular, and from a comparison of the spectra obtained, some mechanistic inferences concerning the aggregation processes have been drawn.
000059841 6531_ $$aion-molecule reactions
000059841 6531_ $$ax-ray structure
000059841 6531_ $$agas-phase
000059841 6531_ $$acarbonyl clusters
000059841 6531_ $$acrystal-structure
000059841 6531_ $$aborane anions
000059841 6531_ $$achemistry
000059841 6531_ $$acomplexes
000059841 6531_ $$areactivity
000059841 6531_ $$acore
000059841 700__ $$0240015$$aDyson, PJ$$g149418
000059841 700__ $$aHearley, AK
000059841 700__ $$aJohnson, BFG
000059841 700__ $$aLangridge-Smith, PRR
000059841 700__ $$aMcIndoe, JS
000059841 773__ $$j43$$k16$$q4962-4973$$tINORGANIC CHEMISTRY
000059841 909CO $$ooai:infoscience.tind.io:59841$$particle$$pSB
000059841 909C0 $$0252010$$pLCOM$$xU9
000059841 937__ $$aLCOM-ARTICLE-2004-012
000059841 970__ $$aISI:000223190300034/LCOM
000059841 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000059841 980__ $$aARTICLE