Carbon monoxide solubility in ionic liquids: determination, prediction and relevance to hydroformylation

The solubility of carbon monoxide in 37 ionic liquids and in some organic solvents has been determined using high-pressure C-13 NMR spectroscopy; a method for predicting the CO solubility is demonstrated, and it was shown that the rate of the hydroformylation of 5-hexen-2-one does not correlate with the CO solubility, as expected from the determined relative solubility of CO compared to H-2.


Published in:
CHEMICAL COMMUNICATIONS, 9, 1070-1071
Year:
2004
ISSN:
1359-7345
Keywords:
Laboratories:




 Record created 2005-11-09, last modified 2018-03-17


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