000059817 001__ 59817
000059817 005__ 20190527110249.0
000059817 022__ $$a1477-9226
000059817 0247_ $$2doi$$a10.1039/B303645F
000059817 037__ $$aARTICLE
000059817 245__ $$aInfluence of the functional group on the synthesis of aminophosphines, diphosphinoamines and iminobiphosphines
000059817 260__ $$c2003
000059817 269__ $$a2003
000059817 336__ $$aJournal Articles
000059817 520__ $$aThe reaction of the anilines RNH2 [R = C6H4(o-CN), C6H4(p-CN), C6H4(m-CN), C6H4(o-C6H5), C6F5 and C6H4(o-CF3)] with Ph2PCl and inorganic or organic bases in differing stoichiometry and in different solvents has been studied. The electronic properties and steric effects of the substituent groups, the base employed, the stoichiometry and the solvent all influence the outcome of the reaction and a series of aminophosphines, diphosphinoamines and iminobiphosphines have been isolated and characterised. The structures of three diphosphinoamines and three iminobiphosphines have been established using single-crystal X-ray diffraction.
000059817 6531_ $$aphosphorus-nitrogen chemistry
000059817 6531_ $$aligands (ph2p)(2)nh dppa
000059817 6531_ $$amixed-metalclusters
000059817 6531_ $$acoordination chemistry
000059817 6531_ $$alithium-salts
000059817 6531_ $$acomplexes
000059817 6531_ $$aamine
000059817 6531_ $$apalladium(ii)
000059817 6531_ $$aplatinum(ii)
000059817 6531_ $$aphosphine
000059817 700__ $$g153598$$aFei, ZF$$0240012
000059817 700__ $$g148592$$aScopelliti, R$$0240189
000059817 700__ $$g149418$$aDyson, PJ$$0240015
000059817 773__ $$q2772-2779$$k13$$tDalton Transactions
000059817 8560_ $$fbeatrice.marselli@epfl.ch
000059817 909C0 $$xU9$$0252010$$pLCOM
000059817 909CO $$pSB$$particle$$ooai:infoscience.tind.io:59817
000059817 937__ $$aLCOM-ARTICLE-2003-013
000059817 970__ $$aISI:000184157800024/LCOM
000059817 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000059817 980__ $$aARTICLE